Solubility Rules

Here is a handy collection of solubility rules for predicting whether or not an ionic compound will or will not dissolve in water. Learn more.

A chart titled "Solubility Rules" outlining soluble and insoluble ionic compound rules, with exceptions specified for each case.

Soluble Compounds: Soluble ionic compounds include those with:

  1. Alkali metal ions (like \(\eNa^⁺\), \(\eK^⁺\), etc.).
  2. The ammonium ion (\({\eN\eH_4}^{⁺}\)).
  3. Chloride, bromide, or iodide ions, EXCEPT when paired with \(\eAg^{+}\), \(\ePb^{2+}\), or \(\eHg_2^{2+}\) ions.
  4. Nitrate, acetate, or chlorate ions, EXCEPT \(\eAg\eC_2\eH_e\eO_2\).
  5. The sulfate ion, EXCEPT when paired with \(\ePb^{2+}\), \(\eCa^{2+}\), \(\eSr^{2+}\), \(\eBa^{2+}\), or \(\eRa^{2+}\) ions.

Insoluble Compounds: Insoluble ionic compounds include those with:

  1. Sulfide ions, EXCEPT when paired with alkali metal, alkaline earth metal, or ammonium ions.
  2. Hydroxide ions, EXCEPT when paired with alkali metal, ammonium, \(\eSr^{2+}\), or \(\eBa^{2+}\) ions.
  3. Phosphate, carbonate, or sulfite ions, EXCEPT when paired with alkali metal or ammonium ions.

Download: Solubility Rules