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Lesson 1: In Search of the Atom
Part c: Subatomic Particles
Part 1a: Democritus to Dalton
Part 1b: The Inside Story of the Atom
Part 1c: Subatomic Particles
The Big Idea
This lesson describes the world of subatomic particles (from electrons to protons and neutrons), explaining how their charges, masses, and roles affect the structure and behavior of atoms in modern chemistry.
Is the Atom Really Indivisible?
We started Lesson 1 by discussing the effort of natural philosophers like Democritus and scientists like John Dalton to establish a reasonable belief in the atom as the indivisible building block of matter. Dalton was indeed successful in convincing the scientific world of the value and validity of thinking in terms of atoms. But the concept of the atom as indivisible was quickly dispelled by the work of J.J. Thomson (1899) and Ernest Rutherford (1911). The atom is not a solid, miniaturized billiard ball with no internal structure or contents. By 1911, it was well understood that the atom contained electrons and protons. And there was plenty of evidence suggesting that there may be a third particle contained in an atom.
Discovery of the Neutron
In 1932, English physicist James Chadwick, a student of Ernest Rutherford, conducted studies of the element beryllium. When bombarding beryllium with alpha particles, Chadwick observed the emission of neutral particles. Chadwick confirmed that the particles had no charge and had a mass similar to the mass of a proton. Chadwick named these particles neutrons.
A Comparison of Three Subatomic Particles
The proton, the neutron, and the electron are the three so-called subatomic particles. The proton and neutron are each approximately 1000 times more massive than the electron. And both are located in the nucleus. This means that nearly all the mass of an atom is located in its very dense center. The positive charge (possessed by protons) is in the nucleus and the negative charge (possessed by electrons) is outside the nucleus. For an electrically neutral atom, the number of electrons must equal the number of protons.

The Empty Space Model
The Rutherford atomic model and the Bohr atomic model are both considered nuclear models. That is, there is a dense, positively charged and massive nucleus at the core of the atom. The electrons are located outside the nucleus. And for both Rutherford and Bohr, those electrons can be thought of as being in orbit. The size of the nucleus is miniscule when compared to the size of the atom. Consider this comparison:
If the nucleus were the size of a golf ball, then the atom would be roughly the size of a professional sports stadium.
Put another way, the atom is about 100 000 times the size of its nucleus. When given these relative dimensions, one can imagine the atom as being primarily empty space.

The Rest of the Story
The story of the atom’s structure will continue in Chapter 5. For now, we need to learn the story of how the elements were organized into the Periodic Table. Continue to the Lesson 2 to learn the story of how a Russian chemist by the name of Dimitri Mendeleev organized the known elements into rows and columns.
Before You Leave - Practice and Reinforcement
Now that you've done the reading, take some time to strengthen your understanding and to put the ideas into practice. Here's some suggestions.
- The Check Your Understanding section below includes questions and problems with answers and explanations and solutions. It provides a great chance to self-assess your understanding.
- Download our Study Card on Subatomic Particles. Save it to a safe location and use it as a review tool.
Check Your Understanding of Subatomic Particles
Use the following questions to assess your understanding of subatomic particles. Tap the
Check Answer buttons when ready.
1. Identify the following statements as being
TRUE or
FALSE. If false, correct the statement or explain what is incorrect about it.
- Most of the charge of the atom is located in the nucleus.
Check Answer
Answer: FALSE
There is an equal amount of charge outside the nucleus as there is inside the nucleus. The charge outside the nucleus is negative and the charge inside the nucleus is positive.
- The nucleus is mostly empty space.
Check Answer
Answer: FALSE
The nucleus is dense with mass. It's volume is small and its mass is relatively large. It is far from being called empty space.
- The proton and the electron have the opposite types of charge.
Check Answer
Answer: TRUE
- The mass of a proton or a neutron is approximately 1000 times the mass of an electron.
Check Answer
Answer: TRUE
- Most of the mass of the atom is located in the nucleus.
Check Answer
Answer: TRUE
- The expanse of an atom consists primarily of empty space.
Check Answer
Answer: TRUE
There may be more going on in that empty space than we really know but it is still fair to suggest that outside the nucleus and to "the edges" of the atom there is a lot of space with little in the way of subtatomic particles being present.
- Most of the volume of the atom is attributed to the size of the nucleus.
Check Answer
Answer: FALSE
The volume of the nucleus is very small in comparison to the volume of the entire atom. The atom's size is like a pinhead in comparison to a football-stadium-sized atom.
- Mass is uniformly distributed throughout the mass of the atom.
Check Answer
Answer: FALSE
Mass is concentrated in the nucleus of the atom. The protons and neutrons are located there. They each have a mass that is approximately 1000 times the mass of the electron.
- The proton and the neutron have the opposite type of charge.
Check Answer
Answer: FALSE
The proton and the electron have the opposite type of charge. The neutron does not possess an overall charge; it is electrically neutral.
- The positive charge of an atom is in the nucleus and the negative charge is outside the nucleus.
Check Answer
Answer: TRUE
- The neutrons are located in the nucleus. The protons and electrons are located outside the nucleus.
Check Answer
Answer: FALSE
The protons and neutrons are located in the nucleus. The electrons are located outside the nucleus.